Kinetics of Cu (II) Transport through Bulk Liquid Membrane with Different Membrane Materials
نویسنده
چکیده
The kinetics of Cu(II) transport through a bulk liquid membrane with different membrane materials was investigated in this work. Three types of membrane materials were used: fresh cooking oil, waste cooking oil and kerosene, each of which was mixed with di-2-ethylhexylphosphoric acid (carrier) and tributylphosphate (modifier). Kinetic models derived from the kinetic laws of two consecutive irreversible first-order reactions were used to study the facilitated transport of Cu(II) across the source, membrane and receiving phases of bulk liquid membrane. It was found that the transport kinetics of Cu(II) across the source phase was not affected by different types of membrane materials but decreased considerably when the membrane materials changed from kerosene, waste cooking oil to fresh cooking oil. The rate constants of Cu(II) removal and recovery processes through the bulk liquid membrane were also determined. Keywords—Transport kinetics, Cu(II), bulk liquid membrane, waste cooking oil.
منابع مشابه
A Kinetic Investigation of a Carrier-Mediated Transport through a Bulk Liquid Membrane
The kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (L) through a bulk liquid membrane is studied experimentally and theoretically. The proposed model is based on the assumption of a pure diffusion of the complex salt [K·L]+SCN¯ through the liquid membrane stagnant films at the interfaces. It illustrates the ...
متن کاملTHE CARRIER FACILITATED TRANSPORT OF THE LITHIUM IONS BY A SERIES OF NON-CYCLIC SYNTHETIC IONOPHORES
The carrier facilitated transport of lithium picrate was studied using a series of non-cyclic polyethers containing different end groups and chain lengths through Bulk Liquid Membrane (BLM) and Supported Liquid Membrane (SLM) systems. The various membrane supports used are viz. PTFE, cellulose nitrate, and dialysis membrane and onion membrane. The amount of Li+ transported depends upon the stru...
متن کاملMass Transfer Mechanism and Mathematical Model for Extraction Process of L-Theanine across Bulk Liquid Membrane
This paper deals with the extraction of L-Theanine containing Aliquat 336 as a carrier and cyclohexane as solvent across bulk liquid membrane. The optimum operation condition are as follows: extraction time of 150 min, initial concentration of theanine in the feed phase is 1.8 g/L, the carrier concentration is 0.5 M, the ion of the receiving phas...
متن کاملSelective Transport of Propylene by Silver Ion Complex Through an Immobilized Liquid Membrane
متن کامل
SELECTIVE TRANSPORT AND EXTRACTION OF ALKALI METAL CATIONS (Na & K ) THROUGH CHLOROFORM LIQUID MEMBRANE BY DIETHYLENE GLYCOL MONOBUTYL ETHER AND DIETHYLENE GLYCOL DIBUTYL ETHER
A liquid membrane containing diethylene glycol monobutyl ether (2) shows specificity for K ion in transport while diethylene glycol dibutyl ether (1) was selective for Na over K . As an extractant, ligand 2 exhibited pronounced extraction selectivity for K over Na in comparison with ligand 1
متن کامل